全文获取类型
收费全文 | 79773篇 |
免费 | 633篇 |
国内免费 | 659篇 |
专业分类
化学 | 25444篇 |
晶体学 | 812篇 |
力学 | 6823篇 |
综合类 | 8篇 |
数学 | 32255篇 |
物理学 | 15723篇 |
出版年
2023年 | 54篇 |
2022年 | 49篇 |
2021年 | 79篇 |
2020年 | 123篇 |
2019年 | 95篇 |
2018年 | 10478篇 |
2017年 | 10310篇 |
2016年 | 6153篇 |
2015年 | 942篇 |
2014年 | 393篇 |
2013年 | 452篇 |
2012年 | 3937篇 |
2011年 | 10658篇 |
2010年 | 5714篇 |
2009年 | 6156篇 |
2008年 | 6696篇 |
2007年 | 8862篇 |
2006年 | 300篇 |
2005年 | 1390篇 |
2004年 | 1572篇 |
2003年 | 1997篇 |
2002年 | 1039篇 |
2001年 | 282篇 |
2000年 | 329篇 |
1999年 | 186篇 |
1998年 | 220篇 |
1997年 | 172篇 |
1996年 | 240篇 |
1995年 | 159篇 |
1994年 | 112篇 |
1993年 | 120篇 |
1992年 | 77篇 |
1991年 | 95篇 |
1990年 | 76篇 |
1989年 | 72篇 |
1988年 | 73篇 |
1987年 | 71篇 |
1986年 | 68篇 |
1985年 | 56篇 |
1984年 | 53篇 |
1983年 | 40篇 |
1982年 | 49篇 |
1981年 | 43篇 |
1980年 | 50篇 |
1979年 | 49篇 |
1914年 | 45篇 |
1913年 | 40篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
71.
72.
73.
74.
Benedict Vasco Normenyo Florian Luca Alain Togbé 《Periodica Mathematica Hungarica》2018,77(2):318-328
In this paper, all base 10 repdigits expressible as sums of three Pell numbers are found. 相似文献
75.
Yingying Zhang Jiarui Wu Siwen Cui Wutao Wei Weihua Chen Rui Pang Zijie Wu Liwei Mi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(3):584-591
Selection of the friction electrode materials is crucial to the performance of a triboelectric nanogenerator (TENG). In the present study, a metal–organic coordination complex containing organosulfonate counteranions with electron-donating ability was synthesized through the coordination-driven self-assembly approach under mild reaction conditions and was chosen as a positive electrode material to construct a triboelectric nanogenerator, exhibiting high-output performance with a peak value of short circuit current density of 98.6 μA and an output voltage of 1180 V. As a practical application, it was shown to light up 1488 commercial green LEDs and power an anticorrosion system device to protect metals from corrosion. 相似文献
76.
Ji Wang Nan Li Yuxia Xu Prof. Dr. Huan Pang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6402-6422
Metal–organic framework (MOF) and covalent organic framework (COF) nanosheets are a new type of two-dimensional (2D) materials with unique design principles and various synthesis methods. They are considered ideal electrochemical devices due to the ultrathin thickness, easily tunable molecular structure, large porosity and other unique properties. There are two common methods to synthesize 2D MOF/COF nanosheets: bottom-up and top-down. The top-down strategy mainly includes ultrasonic assisted exfoliation, electrochemical exfoliation and mechanical exfoliation. Another strategy mainly includes interface synthesis, modulation synthesis, surfactant-assisted synthesis. In this Review, the development of ultrathin 2D nanosheets in the field of electrochemistry (supercapacitors, batteries, oxygen reduction, and hydrogen evolution) is introduced, and their unique dimensional advantages are highlighted. 相似文献
77.
Xinxin Lin Prof. Zheng Fang Cuilian Zeng Chenlong Zhu Xinyan Pang Chengkou Liu Wei He Jindian Duan Ning Qin Prof. Kai Guo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(60):13738-13742
A non-oxidant and metal-free strategy for synthesizing iso-coumarin by using a continuous electrochemical microreactor to initiate an oxidative cyclization reaction of o-(1-alkynyl) benzoate and radicals. This efficient and clean continuous electrosynthesis method not only avoids the complicated gas protection operation and production of by-products in the batch processes, but also help to overcome the difficulty that batch metal catalysis and electrocatalysis are difficult to scale up, and has the potential for pilot-scale experiment. 相似文献
78.
Jing He Mohan Yu Maofu Pang Yanqing Fan Zhe Lian Dr. Ying Wang Prof. Wenguang Wang Prof. Yajun Liu Prof. Hua Jiang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(13):e202103832
Structural designs combining cycloparaphenylenes (CPPs) backbone with planar chiral [2.2]paracyclophane ([2.2]PCP) lead to optical-active chiral macrocycles with intriguing properties. X-ray crystal analysis revealed aesthetic necklace-shaped structures and size-dependent packages with long-range channels. The macrocycles exhibit unique photophysical properties with high fluorescence quantum yield of up to 82 %, and the fluorescent color varies with ring size. In addition, size-dependent chiroptical properties with moderately large CPL dissymmetry factor of 10−3 and CPL brightness in the range of 30–40 M−1 cm−1 were observed. 相似文献
79.
微滴喷射增材制造技术中沉积微滴的大小与均匀性是影响成型件质量的关键因素.本文设计了一种用于生成均匀微滴的压电驱动式微滴喷射装置,通过压电材料带动柔性膜片振动,将液体从喷嘴中喷出生成微滴,采用数值模拟和实验相结合的方法,研究了不同控制参数下膜片振幅及其对生成微滴尺寸和均匀性的影响.研究结果表明:膜片振幅大小受到驱动电压和压电频率的共同影响,压电频率是导致膜片中心点振幅实验测量值小于理论计算值的主要原因,膜片振动会导致喷嘴内部压力发生变化从而影响微滴生成尺寸.在相同驱动电压条件下,压电频率为10 Hz时存在压电膜片振幅最大值.随着膜片振幅的增大,喷孔处液体速度和液柱长度增大到临界值时可以生成微滴,当喷孔处的液柱长度超过临界值时,会形成卫星液滴. 当膜片振幅区间在30 $\mu$m$\sim $42 $\mu $m可以稳定生成微滴,生成最小微滴尺寸为339.8$\mu$m,直径最大变化率为0.29%,相邻两微滴间距最大变化率为2.67%,生成微滴的尺寸及均匀性较好.研究结果有助于提高压电式微滴喷射装置的液滴生成质量. 相似文献
80.